Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 5, Issue 4, Pages 606-609Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b616143j
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An enantioselective Bronsted acid catalyzed Mannich reaction between acetophenone derived enamines and N-Boc imines has been developed. Simple diol (S)-H-8-BINOL 11a has been identified as the optimal catalyst, to afford versatile beta-amino aryl ketones in good yield and enantiomeric excess.
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