4.3 Article

Li2MnO3-stabilized LiMO2 (M = Mn, Ni, Co) electrodes for lithium-ion batteries

Journal

JOURNAL OF MATERIALS CHEMISTRY
Volume 17, Issue 30, Pages 3112-3125

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b702425h

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A strategy used to design high capacity (> 200 mAh g(-1)), Li2MnO3-stabilized LiMO2 (M = Mn, Ni, Co) electrodes for lithium- ion batteries is discussed. The advantages of the Li2MnO3 component and its influence on the structural stability and electrochemical properties of these layered xLi(2)MnO(3)(.)(1-x) LiMO2 electrodes are highlighted. Structural, chemical, electrochemical and thermal properties of xLi(2)MnO(3)(.)(1-x) LiMO2 electrodes are considered in the context of other commercially exploited electrode systems, such as LiCoO2, LiNi0.8Co0.15Al0.05O2, Li1+xMn2-xO4 and LiFePO4.

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