4.6 Article

Total synthesis of capsanthin and capsorubin using Lewis acid-promoted regio- and stereoselective rearrangement of tetrasubsutituted epoxides

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 5, Issue 19, Pages 3207-3212

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b710386g

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The synthesis of capsanthin 1 and capsorubin 2 was accomplished via the C-15-cyclopentyl ketone 6 prepared by Lewis acid-promoted regio- and stereoselective rearrangement of the epoxy dienal 5.

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