Journal
SYNTHESIS-STUTTGART
Volume -, Issue 5, Pages 666-668Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2007-965921
Keywords
epoxide; aziridine; PEG-400; 2-azido alcohol; 2-azido amine
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Ring opening of epoxides and aziridines has readily been carried out at room temperature using poly(ethylene glycol) (PEG400) as the efficient reaction medium to form the corresponding 2-azido alcohols and 2-azido amines, respectively in excellent yields (95-99%) within 30-45 minutes and with high regio- and streoselectivity.
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