Journal
ELECTROCHEMICAL AND SOLID STATE LETTERS
Volume 10, Issue 3, Pages A74-A76Publisher
ELECTROCHEMICAL SOC INC
DOI: 10.1149/1.2424263
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Electrochemical intercalation of PF6(-) into various carbons was studied for the cathode of an Li-ion rechargeable battery. It was found that the capacity of the electrochemical intercalation of PF6(-) increases with decreasing (002) plane distance, namely, increasing the crystallinity of graphitic-carbon, and the largest capacity was achieved on the carbon with almost ideal graphiticcarbon structure. By using graphitic carbon with high crystallinity and the stable electrolyte of ethylene carbonate-dimethylene carbonate, a rechargeable battery with high capacity (90 mAh/g) and rate property was successfully demonstrated. (c) 2007 The Electrochemical Society.
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