Journal
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Volume 633, Issue 11-12, Pages 1757-1761Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/zaac.200700170
Keywords
azido complexes; nitrido complexes; chloroiminato complexes; phosphoraneiminato complexes; homo-; Heteronuclear gold cluster
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Transition metal azido complexes can undergo various reactions of their azido group to yield interesting products. The cleavage of the Na-alpha-N-beta bond and elimination of molecular nitrogen can generate nitrido complexes like MoNCl3 or WNCl3, chloroiminato complexes like Cl3VNCl, or phosphoraneiminato complexes like [Cl4NbNPPh3](2) with metal nitrogen multiple bonds. The reductive elimination of the complete azido group on the other hand may produce metal(0) fragments which in case of gold(I) azido complexes can combine to form clusters.
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