Journal
JOURNAL OF COORDINATION CHEMISTRY
Volume 60, Issue 14, Pages 1579-1586Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958970601089218
Keywords
zinc; nickel; thiosemicarbazone; schiff base
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A new ligand, 4-N-(acetylacetone amine) acetophenone thiosemicarbazone (HL, 1), was synthesized by condensation of p-aminoacetophenone with thiosemicarbazide and acetylacetone. Treatment of HL with zinc acetate and nickel acetate afforded ZnL2 (2) and NiL2 center dot DMF (3). The crystal structures of 1, 2 and 3 have been determined by single-crystal X-ray diffraction. 2 and 3 have similar structures, in which metal atom is coordinated in a distorted tetrahedral configuration, and L- coordinates to zinc(II) or nickel(II) through the azomethine nitrogen and the thiolato sulfur atom.
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