Journal
JOURNAL OF COORDINATION CHEMISTRY
Volume 60, Issue 14, Pages 1557-1565Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958970601086669
Keywords
crystal structure; lead(II); phthalate
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Three new o-phthalate (pht) lead(II) complexes were synthesized and characterized by elemental analyses, IR, H-1 NMR, and C-13 NMR spectroscopy. Single crystal X-ray structural analysis of [Pb(pht)(H2O)](n) shows the complex to be a novel 2D chain polymer as a result of phthalate bridging. Coordination number of Pb(II) is eight, PbO8, with a stereo-chemically active electron lone pair, and the coordination sphere is hemidirected. Packing of this compound in the solid state via pi-pi stacking and hydrogen bonding is discussed.
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