Journal
ELECTROANALYSIS
Volume 19, Issue 1, Pages 91-95Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/elan.200603710
Keywords
sodium diethyldithiocarbamate; cyclic voltammetry; chronoamperometry; anodic oxidation; boron-doped diamond electrode
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An electrochemical study was made of the anodic behavior of sodium diethyldithiocarbamate (DEDTC) using a boron-doped diamond electrode (BDDE) in sodium sulfate supporting electrolyte. This paper presents a new alternative for the electroanalytical determination of DEDTC in protic media, using cyclic voltammetry or chronoamperometry. Linear plots of current vs. concentration correlated with anodic stepwise oxidation were obtained in delimited potential ranges with very good correlation coefficients.
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