Bromide redistribution as influenced by landscape morphology and pedogenic properties in a variable glacial till landscape: A qualitative examination

Whetter, D. A., Bullock, P. R. and Fuller, L. G. 2008. Bomide redistribution as influenced by landscape morphology and pedogenic properties in a variable glacial till landscape: A qualitative examination. Can. J. Soil Sci. 88: 477-490. Redistribution of water and associated solutes in undulating to hummocky landscapes affects crop yield via losses of valuable nutrients and negatively impacts groundwater quality. The objective of this study was to determine the influence of qualitative soil-landscape complexes on vertical and lateral redistribution of solutes in a variable glacial till landscape under zero tillage agricultural management by employing a bromide tracer. Tracer plots were established in the fall of 1999 within three sites comprising three representative soil-slope associations. Values of soil development indicators (A horizon thickness, solum thickness, depth to CaCO3, profile development index and organic carbon) generally increased from crest to midslope to depression. Further to this, the occurrence and thickness of eluvial and illuvial horizons increased from crest to midslope to depression. Well-developed, clay-coated blocky Bt horizons with vertical cracking and overlying Ae horizons in depressions appeared to have favoured rapid, downward vertical bromide redistribution. Crest positions were the least anisotropic and vertical redistribution was more important than lateral redistribution at this position. A combination of topographic and pedologic factors resulted in more lateral redistribution at the midslope position relative to crests and depressions. Bromide recovery rates in the top 60 cm of the soil profile indicated that most of the recovered bromide remained within that depth following spring runoff, but had mostly leached below that depth after the growing season, particularly at the depression position. Low bromide recovery rates in the top 30 cm following spring runoff, indicated that reduced availability of fall-applied nutrients for early crop growth Could be expected at crest and depression positions following spring runoff. Bromide redistribution was important during both spring recharge and over the growing season at the depression position. Bromide movement below crop rooting depths and into shallow groundwater sources provides evidence that fall-applied nutrients can enter groundwater following both spring melt and growing season runoff in depressional landscape positions, especially in recharge areas. Management practices to reduce over-application of soluble nutrients and surface water accumulation, or both, in depressional areas may be an effective means to lower the risk of groundwater contamination with soluble nutrients without jeopardizing crop yield potential across the majority of the landscape positions in undulating to hummocky glacial till terrain.