Journal
CHINESE JOURNAL OF CATALYSIS
Volume 29, Issue 9, Pages 935-939Publisher
SCIENCE CHINA PRESS
DOI: 10.1016/S1872-2067(08)60075-3
Keywords
alcohol; selective oxidation; air; 4-hydroxy-2,2,6,6-tetramethyl-piperidyl-1-oxy; ferric nitrate nonahydrate
Ask authors/readers for more resources
A Fe(NO3)(3)/4-OH-TEMPO catalyst system was developed using the inexpensive organocatalyst 4-hydroxy-2,2,6,6-tetramethyl-piperidyl-1-oxy (4-OH-TEMPO) and the co-catalyst Fe(NO3)(3) center dot 9H(2)O. The catalytic molecular-oxygen-driven oxidation of a broad range of primary and secondary alcohols, which may contain carbon-carbon double bond, N, O, and S heteroatoms, to the corresponding aldehydes and ketones was investigated. The results showed that reaction is highly selective to the desired products when carried out at room temperature in ambient atmosphere air. The mechanism for the catalytic aerobic oxidation of alcohols by Fe (NO3)(3)/4-OH-TEMPO was discussed.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available