Journal
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE
Volume 92, Issue 3, Pages 194-200Publisher
CANADIAN SCIENCE PUBLISHING, NRC RESEARCH PRESS
DOI: 10.1139/cjc-2013-0474
Keywords
N-phosphinoamidinate; ruthenium; ligand design; coordinative unsaturation
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Funding
- Chevron Phillips Chemical Company
- Natural Sciences and Engineering Research Council of Canada
- Dalhousie University
- Killam Foundation
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We report herein on the synthesis and spectroscopic/crystallographic characterization of the first isolable, formally 16-electron Cp*Ru(kappa(2)-P similar to N) species, which are supported by N-phosphinoamidinate ligands. Despite the stability of such complexes, they have been shown to readily coordinate two-electron (L) donors including carbon monoxide and 2,6-xylylisocyanide, affording crystallographically characterized 18-electron Cp*Ru(L)(kappa(2)-P similar to N) adducts. Preliminary reactivity studies confirm that such complexes are capable of extruding hydrogen from ammonia borane.
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