Journal
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE
Volume 89, Issue 6, Pages 645-649Publisher
CANADIAN SCIENCE PUBLISHING, NRC RESEARCH PRESS
DOI: 10.1139/V11-051
Keywords
copper; catalysis; cross coupling; water chemistry; aqueous ammonia; primary arylamine
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Funding
- Nanjing University of Science and Technology
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The copper(I) iodide/1,4-bis(2-hydroxy-3,5-di-tert-butylbenzyl)piperazine (CuI-L2) system catalyzed the cross-coupling reactions between aryl halides and aqueous ammonia in water to produce primary aromatic amines in good yields. The protocol was simple and efficient, avoiding the need for inert atmosphere, additional base, or other additives.
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