Journal
CANADIAN JOURNAL OF CHEMISTRY
Volume 86, Issue 9, Pages 892-898Publisher
CANADIAN SCIENCE PUBLISHING
DOI: 10.1139/V08-097
Keywords
Tridax procumbens; polyacetylene; ionone; flavonol; cytotoxicity; antioxidant activities
Categories
Funding
- National Natural Science Foundation of China [NSFC 20621091]
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Three new phytochemicals, a polyacetylene, 1,2-dihydrodendroarboreol B (1), an ionone derivative, (3S,5R,6S,7E)-3-tetradecanoate-5,6-epoxy-beta-ionone (4), and a flavonol diglycoside, quercetagetin-3,6.4'-trimethoxy-7-O-neohesperidoside (38), along with 35 known compounds with diverse structures, were isolated from the EtOH extract Of the aerial parts of Tridax procumbens. The structures of 1, 4, and 38 were determined on the basis of comprehensive methods including UV, IR, NMR, HR-ESI-MS, and CD, and by comparison of the spectroscopic data with those reported for structurally related compounds. Compounds 4, (3S,5R,6S,7E)-5,6-epoxy-3-hydroxy-7-megastigmene-9-one (5) and icariside B, (12) were tested for their abilities to inhibit SGC-7901 and HL-60 cells. The antioxidant activities of quercetagetin-3,6,4'-trimethoxyl-7-O-beta-D-glucopyranoside (36). quercetin-3-methoxyl-4'-O-beta-D-glucoside (37), and 38 were evaluated by measuring their free-radical-scavenging effects, using the DPPH free-radical method.
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