Journal
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY
Volume 34, Issue 1, Pages 15-19Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.calphad.2009.10.008
Keywords
Alkali metal bromide-cerium bromide systems; Thermodynamic functions of mixing; Phase diagram calculations
Categories
Funding
- Polish Ministry of Science and Higher Education [N N204 4098 33]
Ask authors/readers for more resources
The thermodynamic properties of the ABr-CeBr3 (A = Li-Cs) systems were assessed by the CALPHAD method. The liquid phase in the systems was described by the non-stoichiometric associate model. The entropies of mixing in the liquid ABr-CeBr3 (A = Li, Na) systems are evaluated from experimental data. The entropies of mixing in the liquid ABr-CeBr3 (A = K, Rb, Cs) systems, and the Gibbs energies of formation of pseudobinary compounds: A(3)CeBr(6)(s), A(2)CeCl(5)(s), ACe(2)Cl(7)(s) (A = K. Rb, Cs) were estimated clue to the lack of experimental data. The presence of solid solution near NaBr was predicted from calculations. The nature of the liquid phase and precision of calculations were discussed. (C) 2009 Elsevier Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available