Journal
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY
Volume 32, Issue 3, Pages 470-477Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.calphad.2008.07.002
Keywords
Silicon; Zinc; Manganese; Magnesium; Phase diagrams
Categories
Funding
- General Motors of Canada Ltd
- Natural Sciences and Engineering Research Council of Canada
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The binary Si-Zn and Mn-Si systems have been critically evaluated based upon available phase equilibrium and thermodynamic data, and optimized model parameters have been obtained giving the Gibbs energies of all phases as functions of temperature and composition. The liquid solution has been modeled with the Modified Quasichemical Model (MQM) to account for the short-range-ordering. The results have been combined with those of our previous optimizations of the Mg-Si, Mg-Zn and Mg-Mn systems to predict the phase diagrams of the Mg-Si-Zn and Mg-Mn-Si systems. The predictions have been compared with available data. (C) 2008 Elsevier Ltd. All rights reserved.
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