4.4 Article

Growth and characterization of large CeAlO3 perovskite crystals

Journal

JOURNAL OF CRYSTAL GROWTH
Volume 430, Issue -, Pages 116-121

Publisher

ELSEVIER
DOI: 10.1016/j.jcrysgro.2015.08.025

Keywords

Luminescence; Czochralski method; Edge Defined Film Fed Growth; Single crystal growth; CeAlO3; Perovskites

Funding

  1. CNRS [6598]
  2. National Academy of Sciences of Ukraine [F2-2015]
  3. Marie Sklodovvska-Curie Research, Innovation Staff Exchange Project [1-12020-MSCA-RISE-2014, 644260]
  4. Polish NCN [2012/07/B/ST5/02376]

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This study is focused on obtaining large CeAlO3 single crystals. Using Czochralski and Edge-Defined Film Fed Growth techniques, crystals of length up to 130 mm were obtained. The crystals belong to the tetragonal low temperature modification of CeAlO3 space group P4/mmm, a=3.7669 angstrom, c=3.7967 angstrom. Density and crystallographic parameters as well as some optical, luminescence and magnetic properties of CeAlO3 were studied. The crystals demonstrate rather bright luminescence under UV-excitation, while no luminescence has been registered under X-rays. Ceramic and single crystalline CeAlO3 samples demonstrate p-type conductivity and promising paramagnetic properties. (C) 2015 Elsevier B.V. All rights reserved

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