Journal
RAPID COMMUNICATIONS IN MASS SPECTROMETRY
Volume 22, Issue 2, Pages 130-134Publisher
WILEY
DOI: 10.1002/rcm.3343
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Desorption and ionization efficiencies of matrix-assisted laser desorption/ionization (MALDI) for various biolmolecules with different dihydroxybenzoic acid isomers were studied. No clear relationships were observed between MALDI biomolecule signals vs. gas-phase basicity, proton affinity and ionization potential. This indicates the the gas-phase protonation mechanism is not adequate to explain the observed results. Copyright (c) 2007 John Wiley & Sons, Ltd.
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