Journal
ARKIVOC
Volume -, Issue -, Pages -Publisher
ARKAT USA INC
DOI: 10.3998/ark.5550190.0009.g02
Keywords
Amidines; cytisine; tryptamine; oxydation; 1,2,3-triazole; fungicide activity
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Funding
- Russian Foundation [08-03-00376-a]
- National Natural Science Foundation of China [20672062]
- National Key Project [2003CB114402]
- Tianjin Natural Science Foundation [07JCYBJC01200]
- International Collaboration Program of Tianjin on Science and Technology [07ZCGHHZ01400]
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A general and convenient method for the synthesis of 2-arylhydrazono-2-cyanoacetamidines, containing either a cytisine or tryptamine moiety, or other secondary and primary amines was elaborated. A series of 5-amino-2-aryl-2H-[1,2,3]-triazole-4-carbonitriles was successfully prepared by oxidation of these amidines with copper acetate in pyridine. The screening of the biological activity of the synthesized triazoles and amidines have shown that, some of these compounds possess fungicidal activity at concentrations of 50 mu g/mL against some fungi tested.
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