Journal
BULLETIN OF THE KOREAN CHEMICAL SOCIETY
Volume 35, Issue 7, Pages 1989-1995Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.5012/bkcs.2014.35.7.1989
Keywords
Chiral diamino alcohols; Chiral hydroxyldiamides; Asymmetric allylic oxidation; Small chiral libraries; Chiral pool amino acids
Categories
Funding
- Korean Chemical Society
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The small library of new enantiomerically pure (S,S)-diamino alcohols 1 and their hydroxykliamide precursors 2 were conveniently synthesized on a gram scale from inexpensive and commercially chiral pool amino acids. The catalytic and induced asymmetric effects of the chiral ligands 1 in the asymmetric allylic oxidation of cycloolefins were investigated.
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