4.3 Article

Preparation of Copper Nanoparticles and Catalytic Properties for the Reduction of Aromatic Nitro Compounds

Journal

BULLETIN OF THE KOREAN CHEMICAL SOCIETY
Volume 33, Issue 12, Pages 4003-4006

Publisher

KOREAN CHEMICAL SOC
DOI: 10.5012/bkcs.2012.33.12.4003

Keywords

Copper; Nanoparticles; Catalysis; Nitro reduction; Aromatic amino compounds

Funding

  1. Hebei Provincial Natural Science Foundation of China [B2010000039]
  2. Hebei Education Department [2011121]
  3. Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry

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A novel copper nanoparticles were synthesized from cupric sulfate using hydrazine as reducing reagents. A series of aromatic nitro compounds were reacted with sodium borohydride in the presence of the copper nanoparticles catalysts to afford the aromatic amino compounds in high yields. Additionally, the catalysts system can be recycled and maintain a high catalytic effect in the reduction of aromatic nitro compounds.

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