4.3 Article

Enhanced Visible Light Activity and Stability of TiO2 Nanopowder by co-doped with Mo and N

Journal

BULLETIN OF THE KOREAN CHEMICAL SOCIETY
Volume 33, Issue 4, Pages 1269-1274

Publisher

KOREAN CHEMICAL SOC
DOI: 10.5012/bkcs.2012.33.4.1269

Keywords

co-doping; Molybdenum; TiO2; Stability; Visible light

Funding

  1. National Natural Science Foundation of China [41071317, 30972418]
  2. National Key Technology R & D Programme of China [2007BAC16B07]
  3. Natural Science Foundation of Liaoning Province [20092080]

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A visible light responsive N, Mo co-doped TiO2, were prepared by sol-gel method. X-ray diffraction, TEM, N-2 adsorption, UV-vis spectroscopy, photoluminescence, and X-ray photoelectron spectroscopy were used to characterize the prepared TiO2 samples. Doping restrained the phase transformation from anatase to rutile and reduced the particle sizes. The band gap was much narrowed after N, Mo co-doping. The photocatalytic activities were tested in the degradation of an aqueous solution of a reactive dyestuff, methylene blue, under visible light. The photocatalytic activities of doped TiO2 were much higher than that of neat TiO2. The photocatalytic stability of N, Mo co-doped TiO2, was much better than that of N doped TiO2.

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