Journal
BULLETIN OF THE KOREAN CHEMICAL SOCIETY
Volume 32, Issue 2, Pages 571-575Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.5012/bkcs.2011.32.2.571
Keywords
Graphite-based electrode; Vanadium redox flow battery
Categories
Funding
- Ministry of Knowledge Economy in Korea
- Korea Evaluation Institute of Industrial Technology (KEIT) [2009201010007C] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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Graphite-based electrodes were prepared using synthetic graphite (MCMB 1028) or natural graphite (NG) powder using a dimensionally stable anode (DSA) as a substrate. Their electrochemical properties were investigated in vanadium-based electrolytes to determine how to increase the durability and improve the energy efficiency of redox flow batteries. Cyclic voltammetry (CV) was performed in the voltage range of-0.7 V to 1.6 V vs. SCE at various scan rates to analyze the vanadium redox reaction. The graphite-based electrodes showed a fast redox reaction and good reversibility in a highly concentrated acidic electrolyte. The increased electrochemical activity of the NG-based electrode for the V4+/V5+ redox reaction can be attributed to the increased surface concentration of functional groups from the addition of conductive material that served as a catalyst. Therefore, it is expected that this electrode can be used to increase the power density and energy density of redox flow batteries.
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