4.3 Article

Visible-light Photocatalytic Activity of BiOCl/Bi3O4Cl Nanocomposites

Journal

BULLETIN OF THE KOREAN CHEMICAL SOCIETY
Volume 31, Issue 7, Pages 1941-1944

Publisher

KOREAN CHEMICAL SOC
DOI: 10.5012/bkcs.2010.31.7.1941

Keywords

Photocatalyst; Visible light; BiOCl; Bi3O4Cl; Heterojunction

Funding

  1. Ministry of Environment, Republic of Korea [2009-02002-0051-0]
  2. National Research Foundation of Korea [2009-0076463]
  3. Korea Environmental Industry & Technology Institute (KEITI) [0120090200200510] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
  4. National Research Foundation of Korea [2009-0076463, 과06A1504] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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The heterojunction structures of BiOCl/Bi3O4Cl, exhibiting considerable visible-light photocatalytic efficiency, were prepared by a simple wet-chemical process at ambient condition. The prepared nanocomposites were characterized by XRD, TEM, and UV-visible diffuse reflectance spectra. Under visible light (lambda >= 420 nm) irradiation, BiOCl/Bi3O4Cl exhibited an enhanced photocatalytic activity in decomposing 2-propanol (IP) in gas phase and salicylic acid (SA) in aqueous solution, whereas the bare BiOCl and Bi3O4Cl showed negligible activities. It is deduced that the remarkable visible-light photocatalytic activity of the BiOCl/Bi3O4Cl originates from the hole (h(+)) transfer between VB of the Bi3O4Cl and BiOCl semiconductors.

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