Journal
BULLETIN OF THE KOREAN CHEMICAL SOCIETY
Volume 31, Issue 8, Pages 2351-2356Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.5012/bkcs.2010.31.8.2351
Keywords
Dienamides; Indium; Nitrite; Allylation; Barbier reaction
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Funding
- Ministry of Education, Science and Technology [2010-0015675]
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Various dienamide derivatives were synthesized in reasonable yields from benzonitriles having an amide moiety at the ortho-position, via the sequential (i) In-mediated allylation of nitrite moiety to form an imine intermediate, (ii) intramolecular quenching of an acyl group by the imine intermediate, and (iii) a proton transfer to dienamide.
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