Journal
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
Volume 84, Issue 1, Pages 119-121Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/bcsj.20100253
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Funding
- National Museum of Marine Biology and Aquarium [99200321, 99200322]
- National Dong Hwa University
- Asia-Pacific Ocean Research Center, National Sun Yat-sen University [97C031702]
- National Science Council, Taiwan [NSC 98-2323-B-291-001, 99-2323-B-291-001, 98-2320-B-291-001-MY3]
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A novel clovane-type sesquiterpenoid derivative, rumphellclovane B (1), which possesses an unprecedented delta-lactone moiety, and a new natural clovane, 9 alpha-hydroxyclovan-2-one (2), were isolated from the gorgonian coral Rumphella antipathies. The structures of clovanes 1 and 2 were elucidated by interpretations of spectral data. A plausible biosynthetic pathway between these two compounds was proposed. Compound 1 displayed inhibitory effects on superoxide anion generation by human neutrophils.
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