Journal
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
Volume 83, Issue 1, Pages 42-48Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/bcsj.20090216
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Funding
- Grants-in-Aid for Scientific Research [22750053] Funding Source: KAKEN
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One-dimensional (1D) coordination polymers, M(dhbq)center dot nH(2)O (M = Mg, Mn, Co, Ni, and Zn, H-2(dhbq) = 2,5-dihydroxy-1,4-benzoquinone, n = 2, 2.5, or 3), were synthesized and their structures were investigated using the Rietveld refinement method. They have 1D structure and were isostnictural. From water uptake measurements, thermogravimetry, and elemental analysis, new 2.5 hydrate states were discovered. The proton conductivity of M(dhbq) was found to depend on the metal species and the quantity of absorbed water.
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