Journal
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
Volume 83, Issue 2, Pages 173-175Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/bcsj.20090251
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Funding
- National Natural Science Foundation of China [20721001]
- MSTC [2007CB815301]
- National Science Fund of China for Fostering Talents in Basic Science [J0630429]
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The coexistence of unusual mu(4)- and usual mu(2)-bonding modes of 2-aminopyrazine (NH(2)pyz) is observed for the first time in a novel 3D Ag-I coordination polymer [Ag-4(NHPYZ)(2)(NH2PYZ)(3)(PF6)(2)](n) (1). The structure of 1 possesses 1D {[Ag-4(mu(4)-NHPYZ)(2)](2+)}(n) cylinders which are further extended by mu(2)-NH2PYZ into a 3D framework.
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