Journal
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
Volume 82, Issue 5, Pages 594-599Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/bcsj.82.594
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Funding
- Grant-in-Aid for Scientific Research
- Grants-in-Aid for Scientific Research [21750039] Funding Source: KAKEN
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The cation pools of diarylcarbenium ions have been generated by the low-temperature electrochemical oxidation of diphenylmethane derivatives. In addition to diphenylmethanes having various substituents, 9,10-dihydroanthracene, dibenzosuberane, and xanthenes, which are annulated derivatives of diphenylmethane were also found to serve as a precursor of cation pools. The generation of the diarylcarbenium ion was confirmed by low-temperature NMR analysis and cold-spray mass analysis. Reactivity was also investigated by reactions with various carbon nucleophiles such as allyltrimethylsilane, 1,3,5-trimethylbenzene, and anisole.
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