Journal
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
Volume 81, Issue 10, Pages 1250-1257Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/bcsj.81.1250
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- JSPS Research Fellowship
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The yields of IO radical from the reaction of CH3I with Cl atom in the presence of O-2 were determined as functions of total pressure from 5 to 250 Torr of N-2 diluent and temperature over the range of 278 to 328 K using cavity ring-down spectroscopy. The yields are pressure and temperature dependent. The rate constants and product branching ratios of the reaction of CH2I radical with O-2 were investigated. We determined a rate constant of (1.28 +/- 0.22) x 10(-12) cm(3) molecule(-1) s(-1) at 298 K (2 sigma uncertainty) for this reaction. Theoretical calculations were performed to determine energetics of the reactions of CH2I + O-2, and CH2Br + O-2. The present results suggest that non-negliggible IO radicals will be formed from the reactions of CH3I/CH2I2 + OH/Cl/NO3 at atmospheric conditions.
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