3.9 Article

SYNTHESIS, MAGNETIC AND SPECTROSCOPIC STUDIES of Ni(II), Cu(II), Zn(II) and Cd(II) COMPLEXES OF A NEWLY SCHIFF BASE DERIVED FROM 5-BROMO-2-HYDROXYBEZYLIDENE)-3,4,5-TRIHYDROXYBENZOHYDRAZIDE)

Journal

BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA
Volume 26, Issue 1, Pages 95-101

Publisher

CHEM SOC ETHIOPIA
DOI: 10.4314/bcse.v26i1.10

Keywords

Hydrazone complexes; Schiff base ligand; Spectral studies

Funding

  1. University of Malaya [PPP PS 252/ 2009 A]

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A new hydrazide Shiff base ligand GHL1 (5-bromo-2-hydroxybezylidene)-3,4,5-trihydroxybenzohydrazide) was prepared by refluxing of trihydroxybenzhydrazide with an ethanolic of 5-bromo-2-hydroxybenzaldehyde. The ligand reacted with Ni(II), Cu(II), Zn(II) and Cd(II) (acetate salts). All the complexes were characterized by elemental analysis, molar conductivity, TGA, UV-Vis and FT-IR spectral studies. All the complexes have octahedral geometry except Ni(II) complex which has tetrahedral geometry.

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