Journal
BULLETIN OF MATERIALS SCIENCE
Volume 36, Issue 4, Pages 641-645Publisher
INDIAN ACAD SCIENCES
DOI: 10.1007/s12034-013-0453-4
Keywords
Polyaniline; m-aminobenzoic acid; copolymer; self doping
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In this work, we have deposited poly(aniline-co-m-aminobenzoic acid) on poly(vinyl alcohol) (PVA) by in situ polymerization. The polymerization was effected within maleic acid (MA) cross-linked PVA hydrogel. The copolymer was obtained by oxidative polymerization of aniline hydrochloride and m-aminobenzoic acid using ammonium persulfate as an oxidant. Instead of conventional solution polymerization, here synthesis was carried out on APS soaked MA cross-linked PVA (MA-PVA) film where the polymer was in situ deposited in its conducting form. The composite film was characterized by Fourier transform infra red (FT-IR) and ultraviolet visible (UV-VIS) spectroscopy and electrical measurements. Surface morphology of the composite films was studied by field emission scanning electron microscopy (FESEM). The variation of conductivity of the films was studied.
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