Journal
JOURNAL OF COORDINATION CHEMISTRY
Volume 68, Issue 4, Pages 573-585Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958972.2014.998657
Keywords
Copper(II)-complex; Molecular electro-catalyst; Water reduction; Hydrogen evolution
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Funding
- National Science Foundation of China [20971045, 21271073]
- Student Research Program (SRP) of South China University of Technology [B15-B7050170]
- Science Foundation of Guizhou Province [J-2012-2190]
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The reaction of CuCl(2)2H(2)O and a tetradentate amine phenol ligand affords a dinuclear Cu(II) complex, 1, a new molecular electrocatalyst, whose structure has been determined by X-ray crystallography. Electrochemical studies show that 1 can efficiently produce hydrogen from acetic acid with a turnover frequency (TOF) of 50.1 (in DMF) or from water with a TOF of 104.3 (pH7.0) moles of hydrogen per mole of catalyst per hour.
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