Journal
ARKIVOC
Volume -, Issue -, Pages 205-223Publisher
ARKAT USA INC
DOI: 10.3998/ark.5550190.0011.216
Keywords
Organocatalysis; Michael addition; bifunctional thiourea catalysts; Cinchona alkaloids; Meldrum's acid
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Funding
- National Technology Agency of Finland
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The asymmetric Michael addition of Meldrum's acid to nitroalkenes was studied using a novel type of Cinchona alkaloid-based bifunctional thiourea organocatalyst. The functionality of the thiourea catalysts was also probed by preparing and testing thiourea-N-methylated analogues of the well-known bis-(3,5-trifluoromethyl)phenyl-substituted catalyst.
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