Journal
ARKIVOC
Volume -, Issue -, Pages 160-166Publisher
ARKAT USA INC
DOI: 10.3998/ark.5550190.0011.813
Keywords
Homogeneous catalysis; heterobimetallic catalyst; quinoline; gold catalysis
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Funding
- NASA Glenn Research Center [NAG 3-2930]
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Dimerization of 2-ethynylaniline in the presence of the Ru/Au complexes CpRu(PPh3)Cl(mu-dppm)AuCl or CpRu( PPh3)I(mu-dppm)AuI results in formation of a quinoline derivative. Monometallic model compounds for the Ru and Au centers did not catalyze the dimerization reaction. This transformation proceeds in higher yield in the absence of solvent.
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