4.1 Article

INSIGHT OF THE REMOVAL OF NICKEL AND COPPER IONS IN FIXED BED THROUGH ACID ACTIVATION AND TREATMENT WITH SODIUM OF CLAY

Journal

BRAZILIAN JOURNAL OF CHEMICAL ENGINEERING
Volume 31, Issue 4, Pages 1047-1056

Publisher

SPRINGER HEIDELBERG
DOI: 10.1590/0104-6632.20140314s00001976

Keywords

Bentonite clay; Adsorption; Physicochemical characterization; Metals removal

Funding

  1. CNPq
  2. Foundation for Research Support of Sao Paulo State, FAPESP

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The bentonitic clays show good adsorptive characteristics, being used as alternative material for removing metals. This study evaluates several treatments (calcination, acid activation and treatment with sodium) of bentonite type Bofe in the removal of nickel and copper. Analyses were performed for physicochemical characterization of clay using the techniques: X-ray fluorescence (XRF), thermal analysis (TG and DTA), X-ray Diffraction (XRD), the ethylene glycol monoethyl ether (EGME) method, N-2 adsorption (BET) and Scanning Electron Microscopy (SEM). Among the changes induced by acid activation and sodium transformations, the treatment with sodium chloride in fixed bed showed the highest performance in the monocomponent removal of nickel and copper.

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