4.6 Article

Hydrothermal synthesis of ZnO@polysiloxane microspheres and their application in preparing optical diffusers

Journal

RSC ADVANCES
Volume 5, Issue 22, Pages 17064-17069

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra12217h

Keywords

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Funding

  1. National Natural Science Foundation of China [21306023, 21376051, 21106017, 51077013]
  2. Fund Project for Transformation of Scientific and Technological Achievements of Jiangsu Province of China [BA2011086]
  3. Specialized Research Fund for the Doctoral Program of Higher Education of China [20100092120047]
  4. Key Program for the Scientific Research Guiding Found of Basic Scientific Research Operation Expenditure of Southeast University [3207043101]
  5. Instrumental Analysis Fund of Southeast University

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In this study, optical diffusers based on ZnO@polysiloxane microsphere fillers were successfully prepared by a solvent-free UV curing process. ZnO@polysiloxane microspheres were synthesized via a highly efficient and facile hydrothermal synthetic method. The microscope analysis revealed that the ZnO@polysiloxane microspheres were about 6-8 mu m in diameter. The optical properties of the diffusers were also measured for the first time. The results suggest that the novel diffuser based on ZnO@polysiloxane microsphere fillers possessed suitable light transmittance, good diffusion capacity, and low incident angle dependence. In addition, its tunable optical diffusing capacity relied on the amount of ZnO@polysiloxane microsphere fillers. When the concentration of the ZnO@polysiloxane microspheres was as high as 15 wt%, the diffusing properties of the novel diffusers reached the level of a commercially available diffuser. Therefore, the new fillers can be widely used for the preparation of multifunctional diffusion materials such as touch-panel functions, monitors, military projectors, and TVs.

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