Journal
RSC ADVANCES
Volume 5, Issue 35, Pages 27853-27856Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra04136h
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Funding
- National Science Foundation of China [21272096, 21472080]
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A scalable, operationally easy intermolecular hydrophosphinylation of various unactivated alkenes with H-P(O) compounds via an Ag(I)-initiated free radical process was developed. Mechanistic studies including electron-spin-resonance (ESR) and radical clock experiments suggest that atom transfer processes were involved in this system.
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