Journal
CURRENT GREEN CHEMISTRY
Volume 2, Issue 4, Pages 379-391Publisher
BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/2213346102999150630114117
Keywords
Hirao reaction; P-C coupling; Pd-catalyst; phosphonates; phosphinates; phosphine oxides; P-ligand-free
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Funding
- Hungarian Scientific Research Fund [OTKA K83118]
- [TAMOP 4.2.1/ B-09/1/KMR-2010-0002]
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The Pd-catalyzed P-C couplings of aryl, hetaryl and vinyl derivatives and species with a P(O) H function, typically dialkyl phosphites and secondary phosphine oxides giving rise to phosphonates and phosphine oxides are summarized with special emphasis on the green chemical variations. A great variety of reactions are discussed to demonstrate the different conditions and catalyst systems described. environmentally friendly protocols include the use of a phase transfer catalyst and the microwave technique. The best way is to perform the P-C coupling reactions under Pligand-free and solvent-free conditions.
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