Journal
RSC ADVANCES
Volume 6, Issue 71, Pages 67113-67117Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra12873d
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Funding
- National Natural Science Foundation of China [51303043, 21472031, 21503060]
- Zhejiang Provincial Natural Science Foundation of China [LR14B030001, LY14B020013]
- Science and Technology Department of Zhejiang Province [2015C31138]
- Hangzhou Science and Technology Bureau of China [20140432B04]
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An enantioselective Pd-catalyzed silicon-carbon bond-forming silylation reaction of aryl iodides with hydrosilanes for the synthesis of silicon-stereogenic silanes has been developed, in which a systematic optimization of a TADDOL-derived monodentate phosphoramidite ligand set resulted in the identification of a new TADDOL-derived phosphoramidite ligand that accesses chiral silanes with moderate to good yield and enantioselectivity under mild conditions.
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