Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 7, Issue 7, Pages 4283-4289Publisher
AMER CHEMICAL SOC
DOI: 10.1021/am508678p
Keywords
perovskite; solar cells; NiO; charge transfer and transport
Funding
- EFOR (Iniziativa CNR per il Mezzogiorno) [L. 191/2009 art. 2 comma 44]
- PON-MAAT [PON02_00563_3316357 - CUP B31C12001230005]
- PONFORM@BEYOND-NANO
- Regione PUGLIA (APQ Reti di Laboratorio, project PHOEBUS) [31]
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A spectroscopic investigation focusing on the charge generation and transport in inverted p-type perovskite-based mesoscopic (Ms) solar cells is provided in this report. Nanocrystalline nickel oxide and PCBM are employed respectively as hole transporting scaffold and hole blocking layer to sandwich a perovskite light harvester. An efficient hole transfer process from perovskite to nickel oxide is assessed, through time-resolved photoluminescence and photoinduced absorption analyses, for both the employed absorbing species, namely MAPbI(3-x)Cl(x) and MAPbI(3). A striking relevant difference between p-type and n-type perovskite-based solar cells emerges from the study.
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