Journal
RSC ADVANCES
Volume 6, Issue 39, Pages 32598-32614Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra01536k
Keywords
-
Categories
Funding
- National Key Basic Research Program of China [2013CB934800]
- NSFC [51272260, 51572272]
- NSF of Zhejiang Province [LR14E020004, LY15E020008]
- program for Ningbo municipal science and technology innovative research team [2015B11002, 2014B81004]
Ask authors/readers for more resources
We present a review on some recent studies on the syntheses, structures and properties of amine-functionalized metal-organic frameworks (MOFs), and highlight the benefits of amino functionality towards potential applications. Owing to the strong interaction between CO2 and basic amino functionalities, amine-functionalized MOFs have attracted much attention mainly for CO2 capture. Besides the most widely used in situ synthesis method, post-modification and physical impregnation methods are developed to prepare amine-functionalized MOFs with extremely high CO2 sorption capacity at low pressures. On the basis of the similar mechanism, amine-functionalized MOF-based membranes, including pure amine-functionalized MOF membranes and mixed matrix membranes, exhibit excellent CO2/H-2, CO2/CH4 and CO2/N-2 separation performance. Furthermore, amine-functionalized MOFs also demonstrate potential applications in catalysis.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available