Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 9, Issue 36, Pages 30617-30625Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsami.7b07542
Keywords
lithium-rich layered oxide; bubble-bath reaction; hollow microspheres; cathode materials; lithium-ion batteries
Funding
- Hunan Provincial Key Research and Development Plan [2016GK2012]
- Research Foundation of Education Bureau of Hunan Province [16A001]
- Hunan Provincial Natural Science Foundation of China [2016JJ3008]
- National Science Foundation for Young Scientists of China [51604042, 21601020]
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In the family of high-performance cathode materials for lithium-ion batteries, lithium-rich layered oxides come out in front because of a high reversible capacity exceeding 250 mAh g(-1). However, the long-term energy retention and high energy densities for lithium-rich layered oxide cathode materials require a stable structure with large surface areas. Here we propose a bubble template reaction to build honeycomb-like hollow microsphere architecture for a Li1.2Mn0.32N10.2Co0.08O2 cathode material. Our material is designed with ca.8-mu m-sized secondary particles with hollow and highly exposed porous structures that promise a large flexible volume to achieve superior structure stability and high rate capability. Our preliminary electrochemical experiments show a high capacity of 287 mAh g(-1) at 0.1 C and a capacity retention of 96% after 100 cycles at 1.0 C. Furthermore, the rate capability is superior without any other modifications, reaching 197 mAh g(-1) at 3.0 C with a capacity retention of 94% after 100 cycles. This approach may shed light on a new material engineering for high-performance cathode materials.
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