Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 5, Issue 22, Pages 3263-3266Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8qo00861b
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Funding
- NSFC [21525208, 21472186]
- Henan Normal University [5101034011009, qd16111]
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Rhodium(iii)-catalyzed regio- and chemoselective [5 + 2] annulation between N-(cyanoacetyl)indolines and sulfoxonium ylides has been realized, leading to efficient construction of seven-membered rings under mild conditions. This reaction proceeded via C-H activation with sulfoxonium ylides as carbene synthons.
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