Journal
MATERIALS CHEMISTRY FRONTIERS
Volume 2, Issue 8, Pages 1568-1573Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8qm00220g
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Funding
- Fundamental Research Funds for the Central Universities
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In this work, a disulfide-bridged bispillar[5]arene (A(2)) and tritopic neutral guest molecule (B-3) were synthesized and used to construct supramolecular hyperbranched polymers (SHPs) utilizing pillar[5]arene-based host-guest interactions. In particular, a supramolecular gel with interesting reversible gel-sol transition in response to a temperature change and redox owing to the dynamic host-guest complexation and the characteristics of the disulfide bond can be obtained via the self-assembly behavior of the SHPs under high concentration. Moreover, honeycomb-patterned films can be successfully prepared by utilizing the breath figure method.
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