4.4 Article

Synthesis of (-)-isishippuric acid A, a 4,5-secoquadranoid from a gorgonian coral

Journal

BIOSCIENCE BIOTECHNOLOGY AND BIOCHEMISTRY
Volume 72, Issue 6, Pages 1628-1629

Publisher

TAYLOR & FRANCIS LTD
DOI: 10.1271/bbb.80086

Keywords

isishippuric acid; enantioselective synthesis; sesquiterpenoid; quadrane

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The first synthesis of (-)-isishippuric acid A was accomplished in two steps from a bicyclic synthetic intermediate for isishippuric acid B, which confirmed the structure of isishippuric acid A, including its absolute stereochemistry.

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