Journal
MATERIALS TODAY ENERGY
Volume 8, Issue -, Pages 109-117Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.mtener.2018.03.005
Keywords
All nanocarbon; Li-ion capacitor; High energy density
Funding
- Miisterio de Economia y Competitividad through Fondo Europeo de Desarrollo Regional (FEDER) (MINECO/FEDER) [MAT2015-68394-R]
- AGAUR [NESTOR: 2014_SGR_1505]
- Spanish MINECO through Severo Ochoa Centers of Excellence Program [SEV-2013-0295]
- Marie-Curie Fellowship through Beatriu de Pinos Program from Catalan system of science and technology, Spain [BP-DGR-2013]
- University of Adelaide, Australia
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An energy storage device reaching energy densities of 102 Wh/Kg at power densities of 104 W/Kg would mean the possibility of charging such a device in 36 s. The nanocarbon device presented here is closer to that feat than any previously reported system. N-doped Carbon Nanopipes were used as anode and Partially Reduced Graphene Oxide as cathode, with LiPF6 EC/PC electrolyte. This system yields simultaneously high energy and power densities (262 at 450 W/kg and 78 Wh/kg at 9000 W/kg) which are energy/power combinations considerably higher than those of present Li-ion batteries. Our cell exhibits excellent cycle stability (similar to 91% capacity retention after 4000 cycles 0.01-4 V). These breakthrough results are based on the kinetic balancing of the nanocarbon electrodes, which can deliver excellent high energy density at high rates and low costs. (C) 2018 Elsevier Ltd. All rights reserved.
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