Journal
BIORESOURCE TECHNOLOGY
Volume 155, Issue -, Pages 111-115Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.biortech.2013.12.096
Keywords
Forest biorefinery; Acetic acid; Hemicelluloses; Nanofiltration; Reverse osmosis
Funding
- NSERC
- Atlantic Innovation Fund (AIF)
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This work investigated the feasibility of recovering and concentrating sugars and acetic acid (HAc) from prehydrolysis liquor (PHL) of the kraft-based dissolving pulp process prior to fermentation of hemicellulosic sugars, by the combination of activated carbon adsorption, nanofiltration (NF) and reverse osmosis (RO) processes. To reduce the fouling PHL was subjected to adsorption on activated carbon, then the treated PHL (TPHL) passed through a nanofiltration (NF DK) membrane to retain the sugars, and the permeate of acetic acid rich solution was passed through a reverse osmosis membrane (RO SG). It was found that for NF process sugars were concentrated from 48 to 227 g/L at a volume reduction factor (VRF) of 5 while 80 to 90% of acetic acid was permeated. For the reverse osmosis process, 68% of acetic acid retention was achieved at pH 4.3 and 500 psi pressure and the HAc concentration increased from 10 to 50 g/L. Crown Copyright (C) 2013 Published by Elsevier Ltd. All rights reserved.
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