Journal
COMMUNICATIONS CHEMISTRY
Volume 1, Issue -, Pages -Publisher
NATURE PUBLISHING GROUP
DOI: 10.1038/s42004-018-0084-1
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Funding
- Global Frontier Program through the Global Frontier Hybrid Interface Materials (GFHIM) of the National Research Foundation of Korea (NRF) - Ministry of Science, ICT AMP
- Future Planning [2013M3A6B1078875]
- National Research Foundation of Korea (NRF) - Korea government (MSIP)
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Metal sulfide materials serve as environment-friendly, sustainable, and effective electrode materials for green-energy storage systems. However, their capacity-fading issues related to low electrical conductivity and drastic volume changes during electrochemical cycling have generally limited their application to sodium ion batteries. Here we show that with the combination of an ether-based NaPF6/diglyme electrolyte, the dandelion-shaped manganese sulfide electrode displays enhanced reversible capacity, cycle life, and rate capability. The capacity of 340 mAh g(-1) is maintained over more than 1000 cycles at a current density of 5.0 A g(-1). Furthermore, discharge capacities of 277 and 230 mAh g(-1) at 10 and 20 A g(-1) current densities, respectively, are obtained. Our work demonstrates the formation of a protective solid electrolyte interface layer along the surface of the primary seed particle that limits polysulfide dissolution and hence the preservation of the active material during reaction with sodium.
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