Journal
BIORESOURCE TECHNOLOGY
Volume 102, Issue 22, Pages 10414-10418Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.biortech.2011.08.056
Keywords
Room temperature ionic liquids (RTILs); Biodiesel; Burkholderia cepacia lipase (BCL); Secondary structure; Fourier transform-infrared spectrometry (FT-IR)
Funding
- NSFC [31070709]
- 863 Program [2009AA03Z232]
- Doctoral Education Fund for New Teachers [20090142120090]
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Biodiesel synthesis and conformation of Burkholderia cepacia lipase (BCL) were studied in 19 different room temperature ionic liquids (RTLLs) with a range of cation and anion structures. Overall, anion selection had a greater influence on biodiesel conversion than cation choice. RTILs containing Tf(2)N(-)and PF6- anions were suitable reaction media, while RTIL of [OmPy] [BE4] was the best reaction medium with a biodiesel yield of 82.2 +/- 1.2%. RTILs with strong water miscible properties showed very low biodiesel yields. Conformational analysis by FT-IR revealed that higher biodiesel conversion in RTILs was correlated with a low tendency in alpha-helix content of BCL. An ultrasound-assisted biocatalysis process in RTILs was used to improve mass transfer rate, leading to 83% reduction of the reaction time for biodiesel production. (C) 2011 Elsevier Ltd. All rights reserved.
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